Yes, I do live in France - about 150km NE of Toulouse.
Driving in France is generally great. A lot less traffic once you are away from the cities, and of course lots of fantastic scenery.
Three "downsides". The French tend to drive very close to your tail. Secondly, the speed limit on normal single carriageway roads is 80 kph. Thirdly, gps units are not allowed to show the exact position of speed cameras but have to show a "danger zone". There is a danger zone near to us that is 25km long, and might have a camera anywhere along it. There are warning signs for cameras.
As for places to drive to, it depends on what you want to see and do (and how far you want to drive). It's just possible to drive all the way from the tunnel to the Mediterranean in one day (speed limit on motorways is 130kph in the dry and 110kph in the wet).
Message me if I can help with any more specific information. Pleased to help.