Hello Stuart and welcome to the LOC.
I don't own an RX400h so cannot comment specifically but bear in mind you have very little comeback if you buy privately as opposed to a dealer.
Look for a full (preferably Lexus) service history, I think Lexus also offer a condition report service which may be a good idea pre purchase if buying privately or have an independent inspection carried out by the RAC/AA.
You can also check the MOT history online which is useful is seeing any past failures or advisories or mileage discrepancies with just the make and registration number.
Be aware of any for sale that have lived at or near the coast, we presently have one member with a rotted out rear subframe due to this reason.
Good luck in your search.